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Ce-Doped Smart Adsorbents with Photoresponsive Molecular Switches for Selective Adsorption and Efficient Article

Peng Tan, Yao Jiang, Shi-Chao Qi, Xia-Jun Gao, Xiao-Qin Liu, Lin-Bing Sun

Engineering 2020, Volume 6, Issue 5,   Pages 569-576 doi: 10.1016/j.eng.2020.03.005

Abstract: achieved by introducing photoresponsive azobenzene derivatives with cis/trans isomers to Ce-dopedmesoporous silica.Ce is also doped to provide additional active sites in order to enhance the adsorption performance.

Keywords： Azobenzene     Ce-doped mesoporous silica     Molecular switches     Selective adsorption     Efficient desorption    

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Synthesis of ordered cerium-doped cubic mesoporous silica using long-chain ionic liquid as template

YUE Hongxia, ZHAO Hongmei, LIU Longjiang, WANG Siping, Ruan Qiong, WANG Tongwen

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 2,   Pages 135-139 doi: 10.1007/s11705-008-0031-2

Abstract: ionic liquid 1-hexadecyl-3-methylimidazolium chloride (CmimCl) was used as a template to prepare cerium-dopedThe effect of the amount of Ce salt and CmimCl/Si on the synthesis were discussed in detail.This mesoporous material exhibits a pore architecture which is cubic 3 gyroid and possesses a large surfaceThe CmimCl shows a high tendency toward self-aggregation that allows the formation of the cerium-dopedgyroid mesostructure by using the appropriate amount of Ce salt.

Keywords： mesoporous     CmimCl/Si     tendency     mesostructure     synthesis procedure    

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Enhanced activation of persulfate using mesoporous silica spheres augmented Cu–Al bimetallic oxide particles

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1581-1592 doi: 10.1007/s11705-023-2327-7

Abstract: Herein, Cu–Al bimetallic oxide was synthesized and mixed with mesoporous silica spheres via a simpledispersion spectroscopy, Cu–Al bimetallic oxide was determined as CuO-Al2O3, and mesoporoussilica spheres were found around the these particles.Furthermore, mesoporous silica spheres augment not only enhanced bisphenol A adsorption but also alleviated

Keywords： Cu–Al bimetallic oxides     mesoporous silica spheres     peroxydisulfate     bisphenol A    

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The modification of titanium in mesoporous silica for Co-based Fischer–Tropsch catalysts

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 8,   Pages 1224-1236 doi: 10.1007/s11705-022-2139-1

Abstract: Ordered SBA-15 mesoporous silica with incorporated titanium was successfully synthesized via a one-potThe results showed that titanium was successfully incorporated into the mesoporous silica framework witha limited amount of titanium (Si/Ti > 20), and the mesoporous structure was retained.

Keywords： Fischer–Tropsch synthesis     titanium incorporation     mesoporous silica     metal-support interactions     C   

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Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 8,   Pages 1198-1210 doi: 10.1007/s11705-021-2133-z

Abstract: Sulfonic acid functionalized mesoporous silica based solid acid catalysts with different morphology wereThe sulfonic acid functionalized mesoporous silica catalysts of spherical shape and the cube shape wereIt was sulfonated cubic shape mesoporous silica which exhibited better activity as compared to the sphericalshape silica catalysts.

Keywords： solid acid catalyst     mesoporous silica     sulfonic acid     biodiesel     esterification     oleic acid    

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Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction

Frontiers of Environmental Science & Engineering 2023, Volume 18, Issue 4, doi: 10.1007/s11783-024-1804-7

Abstract:

● Cu-C-MSNs are developed via a co-doping step of Cu with L(+)-ascorbic acid.

Keywords： Cation-π structures     Polarization electric field     Fenton-like process     Contaminants cleavage    

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Transition metal doped mesoporous titania with a crystalline framework as catalysts for oxidation of

YANG Zehui, OU Encai, WANG Yunan, PENG Li, WANG Jiaqiang, YIN Lihui

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 3,   Pages 296-300 doi: 10.1007/s11705-008-0044-x

Abstract: Transition metal M (M = Mn, Fe, Co, Ni, Cu, and Zn) doped mesoporous titania with a crystalline frameworkIt was found that mesoporous TiO doped with those metals (Fe, Co and Ni) whose atomic radii are relatively

Keywords： selectivity     conversion     -bromobenzaldehyde     aqueous hydrogen     oxidation    

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Fe3O4 encapsulated mesoporous silica nanospheres with tunable size and large void

Tingting LIU, Lihong LIU, Jian LIU, Shaomin LIU, Shi Zhang QIAO

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 1,   Pages 114-122 doi: 10.1007/s11705-014-1413-2

Abstract: Magnetic Fe O and mesoporous silica core-shell nanospheres with tunable size from 110–800 nm were synthesizedInterestingly, magnetic core and mesoporous silica shell nanocomposites with large void pore (20 nm)

Keywords： mesoporous silicas     magnetic nanoparticles     core-shell nanoparticles     cell uptake    

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Surface modification of mesoporous silica nanoparticle with 4-triethoxysilylaniline to enhance seawater

Jian Wang, Qun Wang, Xueli Gao, Xinxia Tian, Yangyang Wei, Zhen Cao, Chungang Guo, Huifeng Zhang, Zhun Ma, Yushan Zhang

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 1, doi: 10.1007/s11783-019-1185-5

Abstract: Mesoporous silica nanoparticle was modified with 4-triethoxysilylaniline.Mesoporous silica nanoparticles (MSN), with higher water permeability than NaA zeolite, were used to

Keywords： Thin film nanocomposite membrane     Reverse osmosis     Seawater desalination     Aminophenyl-functionalized mesoporoussilica nanoparticles    

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Crystalline mesoporous transition metal oxides: hard-templating synthesis and application in environmental

Zhen MA, Bei ZHOU, Yu REN

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3,   Pages 341-355 doi: 10.1007/s11783-012-0472-1

Abstract: Mesoporous silicas such as MCM-41 and SBA-15 possess high surface areas, ordered nanopores, and excellentAlthough mesoporous metal oxides have lower surface areas compared to mesoporous silicas, they generallyMesoporous metal oxides can be synthesized via a soft-templating or hard-templating approach, and theseIn this review, we summarize the synthesis of mesoporous transition metal oxides using mesoporous silicas

Keywords： mesoporous materials     silica     metal oxide     hard-templating     environmental catalysis    

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Catalytic activity of cerium-doped Ru/AlO during ozonation of dimethyl phthalate

ZHOU Yunrui, ZHU Wanpeng, CHEN Xun

Frontiers of Environmental Science & Engineering 2008, Volume 2, Issue 3,   Pages 354-357 doi: 10.1007/s11783-008-0059-z

Abstract: influencing the mineralization of dimethyl phthalate (DMP) during catalytic ozonation with a cerium-dopedThe total organic carbon (TOC) removal over the doped catalyst at 100 min reached 75.1%, 61.3% usingResults of experiments on oxidation by ozone alone, adsorption of the catalyst, Ce ion’s and heterogeneouscontribution of heterogeneous catalytic ozonation was about 50%, which showed the obvious effect of Ru–Ce

Keywords： Ru–Ce/AlO     dimethyl phthalate     mineralization     comparison experiment     catalytic ozonation    

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Fabrication of bimetallic Cu–Zn adsorbents with high dispersion by using confined space for gas adsorptive separation

Frontiers of Chemical Science and Engineering   Pages 1623-1631 doi: 10.1007/s11705-022-2202-y

Abstract: but efficient strategy for dispersing active components by using a confined space, which is formed by mesoporoussilica walls and templates in the as-prepared SBA-15 (AS).

Keywords： bimetallic adsorbents     confined space     mesoporous silica     propene/propane separation    

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Magnetic KIT-6 nano-composite and its amino derivatives as convenient adsorbent for U(VI) sequestration

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 2037-2049 doi: 10.1007/s11705-023-2358-0

Abstract: Although mesoporous silica with magnetically hybridized two-dimensional channel structures has been wellfindings of this work further demonstrate the potential broad application prospects of magnetic hybrid mesoporoussilica in radionuclide chelation.

Keywords： magnetic nanoparticle     3D mesoporous silica     amino functionalization     adsorption of U(VI)     acid resistance    

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Enhanced performances in catalytic oxidation of

Nanli QIAO,Xin ZHANG,Chi HE,Yang LI,Zhongshen ZHANG,Jie CHENG,Zhengping HAO

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 3,   Pages 458-466 doi: 10.1007/s11783-015-0802-1

Abstract: A series of hierarchical macro-/mesoporous silica supports (MMSs) were successfully synthesized usingPd was next loaded on the hierarchical silica supports via colloids precipitation method.

Keywords： hierarchical macro-/mesoporous     silica     palladium     VOCs catalytic oxidation    

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Modeling of Ce(IV) transport through a dispersion flat combined liquid membrane with carrier P507

Liang PEI,Liming WANG,Zhanying MA

Frontiers of Environmental Science & Engineering 2014, Volume 8, Issue 4,   Pages 503-509 doi: 10.1007/s11783-013-0540-1

Abstract: A mathematical model for the transport of Ce(IV) from hydrochloric acid solutions through dispersionIn this work, the system is considered to be in a transient state, and chemical reaction between Ce(IVThe experimental and simulated Ce(IV) extractions showed similar tendencies for a high Ce(IV) concentrationand acidity case.The model results indicate that high initial Ce(IV) concentrations and acidity bothhave detrimental effects on Ce(IV) extraction and stripping.

Keywords： membrane (DFCLM)     dispersion phase     feed phase     2-ethyl hexyl phosphonic acid-mono-2-ethyl hexyl ester     Ce    

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Title Author Date Type Operation

Ce-Doped Smart Adsorbents with Photoresponsive Molecular Switches for Selective Adsorption and Efficient

Peng Tan, Yao Jiang, Shi-Chao Qi, Xia-Jun Gao, Xiao-Qin Liu, Lin-Bing Sun

Journal Article

Synthesis of ordered cerium-doped cubic mesoporous silica using long-chain ionic liquid as template

YUE Hongxia, ZHAO Hongmei, LIU Longjiang, WANG Siping, Ruan Qiong, WANG Tongwen

Journal Article

Enhanced activation of persulfate using mesoporous silica spheres augmented Cu–Al bimetallic oxide particles

Journal Article

The modification of titanium in mesoporous silica for Co-based Fischer–Tropsch catalysts

Journal Article

Sulfonic acid-functionalized mesoporous silica catalyst with different morphology for biodiesel production

Journal Article

Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction

Journal Article

Transition metal doped mesoporous titania with a crystalline framework as catalysts for oxidation of

YANG Zehui, OU Encai, WANG Yunan, PENG Li, WANG Jiaqiang, YIN Lihui

Journal Article

Fe3O4 encapsulated mesoporous silica nanospheres with tunable size and large void

Tingting LIU, Lihong LIU, Jian LIU, Shaomin LIU, Shi Zhang QIAO

Journal Article

Surface modification of mesoporous silica nanoparticle with 4-triethoxysilylaniline to enhance seawater

Jian Wang, Qun Wang, Xueli Gao, Xinxia Tian, Yangyang Wei, Zhen Cao, Chungang Guo, Huifeng Zhang, Zhun Ma, Yushan Zhang

Journal Article

Crystalline mesoporous transition metal oxides: hard-templating synthesis and application in environmental

Zhen MA, Bei ZHOU, Yu REN

Journal Article

Catalytic activity of cerium-doped Ru/AlO during ozonation of dimethyl phthalate

ZHOU Yunrui, ZHU Wanpeng, CHEN Xun

Journal Article

Fabrication of bimetallic Cu–Zn adsorbents with high dispersion by using confined space for gas adsorptive separation

Journal Article

Magnetic KIT-6 nano-composite and its amino derivatives as convenient adsorbent for U(VI) sequestration

Journal Article

Enhanced performances in catalytic oxidation of

Nanli QIAO,Xin ZHANG,Chi HE,Yang LI,Zhongshen ZHANG,Jie CHENG,Zhengping HAO

Journal Article

Modeling of Ce(IV) transport through a dispersion flat combined liquid membrane with carrier P507

Liang PEI,Liming WANG,Zhanying MA

Journal Article